first_img Click here to claim your copy now — and we’ll tell you the name of this Top US Share… free of charge! Tom Rodgers has no position in the shares mentioned. The Motley Fool UK has recommended Imperial Brands. Views expressed on the companies mentioned in this article are those of the writer and therefore may differ from the official recommendations we make in our subscription services such as Share Advisor, Hidden Winners and Pro. Here at The Motley Fool we believe that considering a diverse range of insights makes us better investors. Tom Rodgers | Friday, 24th January, 2020 | More on: BT-A IMB SSE Image source: Getty Images Simply click below to discover how you can take advantage of this. I would like to receive emails from you about product information and offers from The Fool and its business partners. Each of these emails will provide a link to unsubscribe from future emails. More information about how The Fool collects, stores, and handles personal data is available in its Privacy Statement. All a FTSE 100 investor has to do to be successful is to beat the average return of the market.It’s certainly easier, in theory, to do that with 10% dividend-paying shares than those that pay 1%. Here I’ll look at the three highest-paying dividend shares on the FTSE 100. But which are value traps, and which offer the best prospects for long-term compound interest gain?5G is here – and shares of this ‘sleeping giant’ could be a great way for you to potentially profit!According to one leading industry firm, the 5G boom could create a global industry worth US$12.3 TRILLION out of thin air…And if you click here we’ll show you something that could be key to unlocking 5G’s full potential…Imperial BrandsTobacco giant Imperial Brands (LSE:IMB) has long paid the highest dividend of any FTSE 100 company. At current count, it stands at 10.6% on a price-to-earnings (P/E) ratio of 7.6. But the share price has taken a battering, cratering 45% in the last three years.Where did it all go wrong? IMB thought they had swerved stricter regulation on smoking by investing heavily in vaping. But this bright future has turned into a nightmare as countries across the globe clamp down and ban e-cigarettes.City analysts like the influential RBC Capital Markets remain “very wary” for the medium to long term, given the uncertain regulatory environment globally. Whoever takes over from 20-year veteran chief executive Alison Cooper after she steps down this year has a hell of a turnaround project on their hands. I would avoid it.BTWith Jeremy Corbyn’s shock plan to nationalise Openreach and give away free broadband dead and buried, BT (LSE:BT.A) can get back to the business of operating the largest phone and internet infrastructure in the UK.An 8.95% dividend on a P/E ratio of just 6.5 might sound like an immediate buy, but investors should be wary. The BT share price has dropped more than 10% since the start of January. The fallout from a disappointing set of half-year results in October 2019 — with revenue down 2% and profits 3% underwater — is still ongoing.There are also serious long-term concerns about the state of BT’s £8.3bn pension shortfall. Previous boss Gavin Patterson gave the go-ahead to repay hundreds of millions of pounds every year for the next 10 years. £2.85bn was paid in 2018, £1.25bn in 2019, with plans for £400m in 2020, £700m in 2021 and 2022, and £907m every year from 2023 to 2030. Clearly this will impact heavily on profitability for at least the next decade. I would avoid BT.SSEOf the shares on this list, SSE (LSE:SSE) is the only one I’d consider.A dividend of 6.4% on a P/E ratio of 22 looks very attractive to me, given where the company is going. Dropping out of the Big Six UK energy providers and selling off one of its major assets doesn’t concern me at all. In fact it’s the main reason I’d buy SSE.Getting newcomer Ovo Energy to pay £500m for its 3.5 million home electricity customers was a masterstroke given the falling revenue and tighter margins in this part of the business. It has refocused instead on the booming renewables market by owning and operating offshore wind farms in Scotland, England, and Ireland.This month analysts Goldman Sachs re-rated SSE higher, noting the “major step-up in public awareness of climate change issues…likely to provide 30 years of growth and regulatory stability“. SSE has “derisked its business model towards more visible activities,” it added.SSE is the only one of these top three dividend-paying FTSE 100 companies really able to achieve sustainable growth for the next three to four decades, in my opinion. I’m sure you’ll agree that’s quite the statement from Motley Fool Co-Founder Tom Gardner.But since our US analyst team first recommended shares in this unique tech stock back in 2016, the value has soared.What’s more, we firmly believe there’s still plenty of upside in its future. In fact, even throughout the current coronavirus crisis, its performance has been beating Wall St expectations.And right now, we’re giving you a chance to discover exactly what has got our analysts all fired up about this niche industry phenomenon, in our FREE special report, A Top US Share From The Motley Fool.center_img The 3 highest-paying FTSE 100 dividend shares and what I’d buy Enter Your Email Address Renowned stock-picker Mark Rogers and his analyst team at The Motley Fool UK have named 6 shares that they believe UK investors should consider buying NOW.So if you’re looking for more stock ideas to try and best position your portfolio today, then it might be a good day for you. Because we’re offering a full 33% off your first year of membership to our flagship share-tipping service, backed by our ‘no quibbles’ 30-day subscription fee refund guarantee. “This Stock Could Be Like Buying Amazon in 1997” Our 6 ‘Best Buys Now’ Shares See all posts by Tom Rodgerslast_img